Experimental solidification of anhydrous latitic and trachytic melts at different cooling rates: The role of nucleation kinetics

Two sets of cooling experiments were run at atmospheric conditions for two anhydrous starting latitic and trachytic melts: 1) five cooling rates (25, 12.5, 3, 0.5, and 0.125 °C/min) between 1300° and 800 °C, and 2) a 0.5 °C/min cooling rate from 1300 °C with quench temperatures at 1200°, 1100°, 1000° and 900 °C. Trachytic run-products are invariably glassy. Nucleation is also suppressed in the latitic run-products at the three highest cooling rates. Conversely, in the 0.5 and 0.125 °C/min runs, latites have a crystal content of  90 vol.%. The phases are: plagioclase, clinopyroxene, glass and iron-bearing oxide (in order of abundance). The variable quench temperatures, investigated by coupling experiments with Pt wire and Pt capsule sample containers in set 2, again did not produce crystallization of trachyte, whereas latitic samples are characterized by  10 vol.% of oxides, pyroxenes and plagioclase (in order of appearance), at temperature < 1000 °C. Effects of (preferential) heterogeneous nucleation on sample holders, of superheating degree, and chemical species loss during cooling are absent for both melt compositions. The difference of solidification paths between these two silicate melts can be ascribed only to their small chemical differences. In comparison with calculated equilibrium conditions all the experimental latitic and trachytic run-products revealed strong kinetic effects, interpretable in the light of the nucleation theory. The glass-forming ability (GFA) of trachyte is higher, whereas their critical cooling rate (Rc) is lower (< 0.125 °C/min), in comparison to latitic melts (Rc > 0.5 °C/min). The experimental results carried out in this study can be applied to lava flows and domes; trachytic lavas are able to flow for longer period with respect to latitic ones in a metastable condition. Glass-rich terrestrial lavas, i.e. obsidians, can be the result of sluggish nucleation kinetics due to the relative high polymerisation of evolved silicate melts.     

Early formed regional antiforms and synforms that fold younger matrix schistosities: their effect on sites of mineral growth

In the metamorphic cores of many orogenic belts, large macroscopic folds in compositional layering also appear to fold one or more pervasive matrix foliations. The latter geometry suggests the folds formed relatively late in the tectonic history, after foliation development. However, microstructural analysis of four examples of such folds suggests this is not the case. The folds formed relatively early in the orogenic history and are the end product of multiple, near orthogonal, overprinting bulk shortening events. Once large macroscopic folds initiate, they may tighten further during successive periods of sub-parallel shortening, folding or reactivation of foliations that develop during intervening periods of near orthogonal shortening. Reactivation of the compositional layering defining the fold limbs causes foliation to be rotated into parallelism with the limbs.Multiple periods of porphyroblast growth accompanied the multiple phases of deformation that postdated the initial development of these folds. Some of these phases of deformation were attended by the development of large numbers of same asymmetry spiral-shaped inclusion trails in porphyroblasts on one limb of the fold and not the other, or larger numbers of opposite asymmetry spirals on the other limb, or similar numbers of the same asymmetry spirals on both limbs. Significantly, the largest disparity in numbers from limb to limb occurred for the first of these cases. For all four regional folds examined, the structural relationships that accompanied these large disparities were identical. In each case the shear sense operating on steeply dipping foliations was opposite to that required to originally develop the fold. Reactivation of the folded compositional layering was not possible for this shear sense. This favoured the development of sites of approximately coaxial shortening early during the deformation history, enhancing microfracture and promoting the growth of porphyroblasts on this limb in comparision to the other. These distributions of inclusion trail geometries from limb to limb cannot be explained by porphyroblast rotation, or folding of pre-existing rotated porphyroblasts within a shear zone, but can be explained by development of the inclusion trails synchronous with successive sub-vertical and sub-horizontal foliations.     

气球携带碘化银焰弹技术研究

主要介绍在北京地区开展气球携带碘化银焰弹雨雪作业的作业技术，经济效益等问题。通过各种增雨雪技术比较，认敢球携带碘化银焰弹增雨雪作业在北方干旱地区的抗旱工作中或作为收音机增雨雪作业的补充手段具有应用价值     

含AgI焰剂成冰性能与物化特征的实验研究

利用CAMS的1 m~3等温云室系统筛选出新型高效AgI焰剂WMC-IN-001和WMG-IN-002。检测结果表明,它们具有较高的成核率,在-15℃时达到10~(15)g~(-1)AgI量级,尤其在-7℃时WMC-IN-001的成核率仍可达到10~(14)g~(-1)AgI量级。同时给出对节银剂配方和2011年市场上主要的几种催化剂的检测结果进行对比。WMC-IN-001和WMC-IN-002的成冰速率较慢,在各检测温度的成冰速率差异较小,均在40~55 min。利用冷场发射扫描电镜和能谱仪对WMC-IN-001燃烧产生的气溶胶粒子作了物化特征分析,粒子分布在0.02~0.60μm,具有两个典型的模态:0.02~0.10μm的较小的粒子和0.20~0.55μm的较大的粒子,均立方直径为0.2472μm。WMC-IN-001气溶胶粒子明显偏大,小粒子相对较少,这可能是其成冰速率偏慢的原因之一。     

利用双线偏振雷达分析人工防雹作业效果

以北京市平谷区2011年6月11日防雹作业为例,利用双线偏振雷达资料,选取与作业区条件十分接近的云块为对比区,根据回波移动方向和速度,跟踪分析在不同高度上防雹作业前后云体宏观结构特征和粒子相态等微物理变化过程。作业后云体所呈现特征为:1作业区的云顶高度、强回波中心高度迅速下降,对比区变化不明显;2作业区水平反射率Zh减小,差分反射率Zdr、零相关系数ρhv增大,单位差分传播相移Kdp小范围内波动,对比区Zh、Zdr、Kdp变化不明显;ρhv增大;3作业区对流减弱,高层较大冰雹粒子、大雨滴下沉明显,最终以霰粒子为主;而对比区域则对流仍然旺盛,冰雹粒子有增多趋势。以上特征表明防雹作业可有效抑制冰雹胚胎成长为冰雹的过程,通过偏振雷达观测参量可对防雹作业效果进行较好的验证。     

A garnet population in Yellowknife schist, Canada

Abstract Data are presented on a garnet population in a specimen of garnet-biotite-plagioclase-quartz schist from the cordierite zone of an Archaean thermal dome in the Southern Slave Province of the Canadian Shield. Garnet crystals are bounded by planar dodecahedral faces and by trapezohedral faces which on the 10-μm scale are corrugated. Crystal distribution, as revealed by dissection of a small cubic volume of rock, is random. The size distribution is normal, with a mean diameter of 0.81 mm and a standard deviation of 0.32 mm. In the largest crystal of the population (mean radius 0.83 mm), [Mn] = 100 Mn/(Fe + Mg + Mn + Ca) decreases from 14.5 at the centre to 7.5 and then increases in the outer margin to 8.5; [Fe] increases continuously from 67 at the centre to 77 at the surface; [Mg] increases from 12.5 to 13.5 and then falls sharply to 11; [Ca] remains unchanged at 4.0 and then drops to 3.3. Progressively smaller crystals have progressively lower [Mn] and higher [Fe] concentrations at their centres, while all crystals have the same margin composition. Growth vectors extending from given concentration contours to crystal surfaces are of equal length regardless of the size of the crystal in which the vector is located. A garnet-forming model is presented in which reaction was initiated by a rise in temperature. Nucleation sites were randomly selected. The nucleation rate increased with time and then declined. Crystal faces advanced at a constant linear rate, which implies an increase in volume proportional to surface area. Initially, the composition of garnet deposited on crystal surfaces was determined by van Laar equations of equilibrium, which demanded the withdrawal of Mn and Fe from within chlorite crystals. This transfer reaction was then accompanied by an ion exchange reaction which moved Mn and Fe to garnet surfaces from biotite, in exchange for Mg. The exchange reaction provides an explanation for the high overall concentration of Mn and Fe in garnet and for the observed Mn and Mg reversals in the margins of crystals. The increase of garnet volume in the garnet population is found to be parabolic, i.e. Vαα⁵.     

The influence of aerosol particle composition on cloud droplet formation

A difference in partitioning between cloud droplets and interstitial air for two chemical species (elemental carbon and sulphur) with different expected behaviour in nucleation scavenging was observed in clouds at Mt. Kleiner Feldberg (825 m asl), near Frankfurt, Germany. The fraction of sulphur incorporated in cloud droplets was always higher than the fraction of elemental carbon. This difference in partitioning has also been observed in fog but under different pollution conditions in the Po Valley, Italy. Both these studies were based on bulk samples. In the present study at Kleiner Feldberg, impactor samples of the particles in the interstitial air and the cloud droplet residuals were taken and a single particle analysis was done on the samples. It was found that, for a given particle size, the majority of particles forming cloud droplets were soluble and that insoluble particles preferentially remained in the interstitial air.     

THE STUDY OF HIGH EFFICIENT AgI PYROTECHNICS AND THEIR NUCLEATING PROPERTIES*

Two kinds of high efficient Agl pyrotechnics BR-88-5 and BR-91-Y have been developed.The tests in the cloud chamber show that the AgI ice nucleating effectiveness can reach up to 10¹⁵/g,and the BR-91-Y has even higher ice nucleating rate.Two kinds of foreign AgI pyrotechnics have been made according to the given formulations and also tested in the cloud chamber for comparison.X-ray diffraction analysis for the aerosols produced by burning BR-91-Y shows that AgI in acrosols still retains the hexagonal crystal form and the lattice parameters are smaller than those of pure AgI and other AgI composite nuclei,and closer to ice.Combining with the other tests,the reasons for the high efficiency of BR-91-Y have been discussed.     

鄂西北对流云及其人工催化的三维数值模拟个例研究

该文把三维对流云模式应用于湖北省西北部地区的对流云降水研究和人工增雨试验设计，并和张家口冰雹云个例的模拟进行了比较。模拟结果表明该地区给定季节的对流云主要特征有云底温度（约26℃)。云中上升气流速度中等（最大约18m/s)，初始回波在较暖区1～-2.5℃)形成，云的回波顶高约13km。前期的暖支降水对地面雨量贡献很大。播云的数值模拟结果显示了初始回波出现后约10min回波项高到达-22℃处时，在温度为-2～-6℃层的支的中心部位引进5×105～107个/kg碘化银冰核，使地面降雨只有身长弱增加。湖北西北部对流云中过冷云水偏少，最大仅5g/kg和3.8g/kg,面且过冷云水大值区温度偏高（-2.5℃).催化后云中最大上升气流和地面格点最大雨量值变化不大，有时减少，后期降雨量增加，下风方雨量增加，分布更加均匀，但总雨量增加不多。